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Which of the following pairs are position isomers? I. .......................O.......................||CHX3−CHX2−CHX2−CHX2−C−H II. .................O.................||CHX3−CHX2−CHX2−C−H

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प्रश्न

Which of the following pairs are position isomers?

I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

(i) I and II

(ii) II and III

(iii) II and IV

(iv) III and IV

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उत्तर

(ii) II and III

Explanation:

In position isomerism, two or more compounds differ in the position of substituent, functional group or multiple bonds but molecular formula is same. In pentanone-2 and pentanone-3, position of ketonic group is different.

CH3 – CH2 – CH2 – CO – CH3 and CH3 – CH2 – CO – CH2 – CH3

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अध्याय 12: Organic Chemistry Some Basic Principles and Techniques - Multiple Choice Questions (Type - I) [पृष्ठ १४८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
अध्याय 12 Organic Chemistry Some Basic Principles and Techniques
Multiple Choice Questions (Type - I) | Q 19 | पृष्ठ १४८

संबंधित प्रश्न

Write IUPAC name of the product obtained by the ozonolysis of the following compound:

3,4-Dimethyl-hept-3-ene


Write IUPAC name of the product obtained by the ozonolysis of the following compound:

2-Ethylbut-1-ene 


Find out the type of isomerism exhibited by the following pair.

CH3 – CH2 – NH – CH2 - CH3 and CH3 - NH - CH2 - CH2 - CH3


Find out the type of isomerism exhibited by the following pair.


Choose the correct option.

Which type of isomerism is possible in CH3 CHCHCH3?


Molecular formula of the functional isomer of methyl formate is ____________.


What type(s) of isomerism is(are) shown by [Co(NH3)4Br2]Cl?


But-1-ene and But-2-ene are examples of ____________.


The type of isomerism possible in 2-butene is ____________.


What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?


What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]

\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]


In which of the following, functional group isomerism is not possible?


Which of the following pairs are not functional group isomers?

I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

(i) II and III

(ii) II and IV

(iii) I and IV

(iv) I and II


Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds which are functional group isomers.


Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds that represents position isomerism.


Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds that represents chain isomerism.


Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by

CH3 – S – CH2 – CH2 – CH3

And 

\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]


The molecules having dipole moment are:

(i) 2,2-Dimethylpropane

(ii) trans-Pent-2-ene

(iii) cis-Hex-3-ene

(iv) 2, 2, 3, 3 - Tetramethylbutane.


Tautomerism is exhibited by ______. 


Which of the following does NOT exhibit geometrical isomerism? 


The compound which shows metamerism is ______


Which type of isomerism can not be shown by benzaldoxime?


Which one of the following pairs are called position isomers?


The correct stereochemical name of


How many structural isomers possible of the molecular formula C3H6O (excluding enol form)?


The number of acyclic structural isomers (including geometrical isomers) for pentene are ______.


Which of the following pairs of compounds are positional isomers?


Which of the following reactions will not produce a racemic product?


The number of geometrical isomers from [Co(NH3)3(NO2)3] is ______.


Which of the following pairs of compounds is an example of position isomerism?


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