Advertisements
Advertisements
प्रश्न
What is meant by the following term? Give an example of the reaction in the following case.
Oxime
Advertisements
उत्तर
Oximes are formed by reaction between aldehydes or ketones and hydroxylamine. The reaction is carried out in a mildly acidic condition.
\[\begin{array}{cc}
\ce{H3C}\phantom{...........................}\ce{H3C}\phantom{.....................}\\
\backslash\phantom{..............................}\backslash\phantom{................}\\
\ce{= O + \underset{Hydroxylarnine}{H2N-OH} ->[pH 3.5] \phantom{......}= NOH + H2O}\\
/\phantom{..............................}/\phantom{.................}\\
\ce{H}\phantom{............................}\ce{\underset{Oxime}{H}}\phantom{..................}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
Write the products formed when CH3CHO reacts with the following reagents : H2N – OH
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
What is meant by the following term? Give an example of the reaction in the following case.
Hemiacetal
What is meant by the following term? Give an example of the reaction in the following case.
Ketal
Write balanced chemical equations for action of ammonia on - acetaldehyde
Write balanced chemical equations for action of ammonia on - acetone
What is the action of the following reagents on ethanoic acid?
1) `LiAlH_4"/"H_3O^+`
2) `PCl_3 , "heat"`
3) `P_2O_5, "heat"`
What are amines?
Give a simple chemical test to distinguish between 
Identify the compounds A, B and C in the following reaction.
\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]
The pH of blood does not appreciably change by a small addition of acid or base because
Which of the following has the most acidic hydrogen?
Acetaldehyde and acetone differ in their reaction with
Paraldehyde is formed as a result of polymerisation:-
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw structure of the following derivative.
Acetaldehydedimethylacetal
Draw structures of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
