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प्रश्न
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\end{array}\]
- Write the IUPAC name of the product.
- State the rule that governs the formation of this product.
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उत्तर
- IUPAC name of the product: 1-Bromo-2-methylpropane
- Anti-Markownikov’s rule/Kharasch effect/peroxide effect: It states that the addition of HBr to an unsymmetrical alkene in the presence of organic peroxide (R–O–O–R) takes place in the opposite orientation to that suggested by Markovnikov's rule.
APPEARS IN
संबंधित प्रश्न
Write IUPAC names of the products obtained by the reaction of cold concentrated sulphuric acid followed by water with the following compounds.
Propene
Write the reaction to convert propene to isopropyl alcohol.
The compound that will react most readily with gaseous bromine has the formula (NEET) ______.
Which among the following alkenes on reductive ozonolysis produces only propanone?
Give IUPAC name for the following compound.
\[\begin{array}{cc}\ce{C2H5}\phantom{.}\ce{CH3}\phantom{.......}\\|\phantom{.....}|\phantom{.........}\\
\ce{CH3 - C - C - C ≡ C - CH3}\\
|\phantom{.....}|\phantom{.........}\\
\ce{CH3}\phantom{..}\ce{H}\phantom{.........}
\end{array}\]
Explain Markow nikoff’s rule with suitable example.
Complete the following:
\[\ce{2 - butyne ->[Lindlar Catalyst]}\]
Alkene \[\ce{R - CH = CH2}\] reacts with B2H6 in the presence of dilute H2O2, to give:
Identify the CORRECT statement about the following compound.
(C2H5)2NH
Saytzeff's rule states that ____________ product is the major product in dehydrohalogenation of an alkyl halide.
\[\ce{CH3CH2CH = CH2 ->[B2H6][H2O, H2O2, OH^-] X}\]
What is X?
Which of the following compounds will show cis-trans isomerism?
The major product obtained in the photo catalysed bromination of 2-methylbutane is ______.
Which of following properties is not exhibited by benzene?
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
What is the action of following on but-2-ene?
dil alkaline KMnO4
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
Write the balanced chemical reaction for preparation of ethane from Ethyl magnesium iodide.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\
\phantom{...........................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
What is the action of following on but-2-ene?
dil. alkaline KMnO4
Write the reaction to convert propene to isopropyl alcohol.
What is the action of following on but-2-ene?
dil. alkaline KMnO4
What is the action of following on but-2-ene ?
dil. alkaline \[\ce{KMnO4}\]
