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प्रश्न
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\end{array}\]
- Write the IUPAC name of the product.
- State the rule that governs the formation of this product.
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उत्तर
- IUPAC name of the product: 1-Bromo-2-methylpropane
- Anti-Markownikov’s rule/Kharasch effect/peroxide effect: It states that the addition of HBr to an unsymmetrical alkene in the presence of organic peroxide (R–O–O–R) takes place in the opposite orientation to that suggested by Markovnikov's rule.
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संबंधित प्रश्न
Write IUPAC names of the products obtained by the reaction of cold concentrated sulphuric acid followed by water with the following compounds.
Propene
Write the reaction to convert propene to n-propyl alcohol.
Write the reaction to convert propene to isopropyl alcohol.
Which among the following alkenes on reductive ozonolysis produces only propanone?
Peroxide effect (Kharasch effect) can be studied in case of ______.
Explain Markow nikoff’s rule with suitable example.
Complete the following:
\[\ce{CaC2 ->[H2O]}\]
Which of the following does NOT observe the Markovnikov's addition of HBr?
What is the main product of the reaction between 2-Methylpropene with HBr?
\[\ce{A + HBr ->[Peroxide] 1-Bromo-2-methylheptane}\]
Identify A.
What is the major product formed by HI on reaction with \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-CH = CH2}\\
|\phantom{.......}\\
\ce{H3C}\phantom{.........}
\end{array}\]?
Which of following properties is not exhibited by benzene?
What is the action of following on but-2-ene?
dil alkaline KMnO4
What is the action of following on but-2-ene?
dil alkaline KMnO4
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Write the balanced chemical reaction for preparation of ethane from Ethyl magnesium iodide.
What is the action of following on but-2-ene?
dil alkaline KMnO4
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{...............................}\ce{CH3}\\
\phantom{............................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
What is the action of following on but-2-ene?
dil alkaline \[\ce{KMnO4}\]
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\
\phantom{...........................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
What is the action of following on but-2-ene?
dil. alkaline KMnO4
Write the reaction to convert propene to isopropyl alcohol.
