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प्रश्न
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\end{array}\]
- Write the IUPAC name of the product.
- State the rule that governs the formation of this product.
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उत्तर
- IUPAC name of the product: 1-Bromo-2-methylpropane
- Anti-Markownikov’s rule/Kharasch effect/peroxide effect: It states that the addition of HBr to an unsymmetrical alkene in the presence of organic peroxide (R–O–O–R) takes place in the opposite orientation to that suggested by Markovnikov's rule.
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संबंधित प्रश्न
Write the reaction to convert propene to n-propyl alcohol.
Write the reaction to convert propene to isopropyl alcohol.
Which among the following alkenes on reductive ozonolysis produces only propanone?
Give IUPAC name for the following compound.
\[\ce{CH3 –CH=CH–CH=CH–C≡C–CH3}\]
Give IUPAC name for the following compound.
\[\begin{array}{cc}\ce{C2H5}\phantom{.}\ce{CH3}\phantom{.......}\\|\phantom{.....}|\phantom{.........}\\
\ce{CH3 - C - C - C ≡ C - CH3}\\
|\phantom{.....}|\phantom{.........}\\
\ce{CH3}\phantom{..}\ce{H}\phantom{.........}
\end{array}\]
Which of the following does NOT observe the Markovnikov's addition of HBr?
Alkene \[\ce{R - CH = CH2}\] reacts with B2H6 in the presence of dilute H2O2, to give:
\[\ce{CH3CH2CH = CH2 ->[B2H6][H2O, H2O2, OH^-] X}\]
What is X?
Addition of HCl to ____________ mainly gives 2-chloro-2-methylbutane.
What is the major product formed by HI on reaction with \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-CH = CH2}\\
|\phantom{.......}\\
\ce{H3C}\phantom{.........}
\end{array}\]?
Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is ______.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
What is the action of following on but-2-ene?
dil alkaline \[\ce{KMnO4}\]
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\
\phantom{...........................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
What is the action of following on but-2-ene?
dil. alkaline KMnO4
Write the reaction to convert propene to isopropyl alcohol.
What is the action of following on but-2-ene?
dil. alkaline KMnO4
What is the action of following on but-2-ene ?
dil. alkaline \[\ce{KMnO4}\]
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{...............................}\ce{CH3}\\
\phantom{............................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH_2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
