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प्रश्न
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\end{array}\]
- Write the IUPAC name of the product.
- State the rule that governs the formation of this product.
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उत्तर
- IUPAC name of the product: 1-Bromo-2-methylpropane
- Anti-Markownikov’s rule/Kharasch effect/peroxide effect: It states that the addition of HBr to an unsymmetrical alkene in the presence of organic peroxide (R–O–O–R) takes place in the opposite orientation to that suggested by Markovnikov's rule.
APPEARS IN
संबंधित प्रश्न
Write IUPAC names of the products obtained by the reaction of cold concentrated sulphuric acid followed by water with the following compounds.
Propene
Write the reaction to convert propene to isopropyl alcohol.
Peroxide effect (Kharasch effect) can be studied in case of ______.
Give IUPAC name for the following compound.
\[\begin{array}{cc}\ce{C2H5}\phantom{.}\ce{CH3}\phantom{.......}\\|\phantom{.....}|\phantom{.........}\\
\ce{CH3 - C - C - C ≡ C - CH3}\\
|\phantom{.....}|\phantom{.........}\\
\ce{CH3}\phantom{..}\ce{H}\phantom{.........}
\end{array}\]
Complete the following:
\[\ce{2 - butyne ->[Lindlar Catalyst]}\]
Complete the following:
\[\ce{CaC2 ->[H2O]}\]
Which of the following does NOT observe the Markovnikov's addition of HBr?
What is the main product of the reaction between 2-Methylpropene with HBr?
Saytzeff's rule states that ____________ product is the major product in dehydrohalogenation of an alkyl halide.
Addition of HCl to ____________ mainly gives 2-chloro-2-methylbutane.
The major product obtained in the photo catalysed bromination of 2-methylbutane is ______.
Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is ______.
Which of the following in Baeyer's reagent?
What is the action of following on but-2-ene?
dil alkaline KMnO4
What is the action of following on but-2-ene?
dil alkaline KMnO4
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
What is the action of following on but-2-ene?
dil alkaline KMnO4
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
What is the action of following on but-2-ene?
dil alkaline \[\ce{KMnO4}\]
What is the action of following on but-2-ene?
dil alkaline \[\ce{KMnO4}\]
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\
\phantom{...........................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
Write the reaction to convert propene to isopropyl alcohol.
Write the reaction to convert propene to isopropyl alcohol.
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{...............................}\ce{CH3}\\
\phantom{............................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH_2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
