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प्रश्न
Explain why Anhydrous FeCl3 cannot be prepared by heating hydrated iron (III) chloride.
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उत्तर १
On heating the hydrate, HCl acid is released and basic salt (FeOCl) or ferric oxide remains. Hence, anhydrous ferric chloride cannot be prepared by heating the hydrate.
उत्तर २
Heating hydrated Iron (III) chloride cannot produce anhydrous FeCl3, but instead creates FeCl3.6H2O, Fe2O3.H2O, and HCl.
\[\ce{2[FeCl3.6H2O]->[\Delta] Fe2O3 + 9H2O + 6HCl}\]
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संबंधित प्रश्न
Name the procedure used to prepare a sodium salt such as sodium sulphate.
The following is a list of methods for the preparation of salts.
A – direct combination of two elements
B – reaction of a dilute acid with a metal.
C – reaction of a dilute acid with an insoluble base.
D – titration of a dilute acid with a solution of soluble base.
E – reaction of two solutions of salts to form a precipitate.
Choose from the above list A to E, the best method of preparing the following salt by giving a suitable equation in the following case:
Anhydrous ferric chloride.
Give the preparation of the salt shown in the left column by matching with the methods given in the right column. Write a balanced equation for each preparation.
| Salt | Method of preparation |
| Zinc Sulphate | Precipitation |
| Ferrous sulphide | Oxidation |
| Barium Sulphate | Displacement |
| Ferric sulphate | Neutralisation |
| Sodium sulphate | Synthesis |
Choose the method of preparation of the following salts, from the methods given in the list:
[List : A. Neutralization B. Precipitation C. Direct combination D. Substitution ]
(i) Lead chloride
(ii) Iron (II) sulphate
(iii) Sodium nitrate
(iv) Iron (III) chloride
Define the following term:
Neutralisation
Choosing the correct words given in brackets, complete the sentence given below: Sodium sulphate from sodium carbonate.
Fill in the blanks with suitable words:
An acid is a compound which when dissolved in water forms hydronium ions as the only ______ ions. A base is a compound which is soluble in water and contains ______ ions. A base reacts with an acid to form a ______ and water only. This type of reaction is known as ______.
Match the salts underlined in Column A with the most suitable method of preparation given in Column B.
| Column A | Column B | ||
| (a) | \[\ce{ZnCl2 \text{from} Zn}\] | 1. | Precipitation |
| (b) | \[\ce{KNO3 \text{from} KOH}\]. | 2. | Direct combination |
| (c) | \[\ce{CaCO3 \text{from} CaCl2}\]. | 3. | Displacement reaction |
| 4. | Neutralization |
You are provided with the following chemicals:
NaOH, Na2CO3, H2O, Zn(OH)2, CO2, HCI, Fe, H2SO4, CI2, Zn.
Using the suitable chemicals from the given list only, state briefly how you would prepare sodium chloride.
For each of the salt: A, B, C and D, suggest a suitable method of its preparation.
D is a soluble salt of zinc.
