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प्रश्न
Discuss the trend of the following:
The solubility and the nature of oxides of Group 2 elements.
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उत्तर
All the alkaline earth metals form oxides of formula MO. The oxides are very stable due to high lattice energy and are used as refractory material. Except BeO (predominantly covalent), all other oxides are ionic and their lattice energy decreases as the size of cation increases.
The oxides are basic and basic nature increases from BeO to BaO (due to increasing ionic nature).
`ubrace(BeO <)_("Amphoteric") ubrace(MgO <)_("Weakly basic") ubrace(CaO < SrO < BaO)_("Strongly basic")`
BeO dissolves both in acid and alkalies to give salts and is amphoteric.
The oxides of the alkaline earth metals (except BeO and MgO) dissolve in water to form basic hydroxides and evolve a large amount of heat. BeO and MgO possess high lattice energy and thus are insoluble in water.
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संबंधित प्रश्न
Discuss the general characteristics and gradation in properties of alkaline earth metals.
Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?
The product obtained as a result of a reaction of nitrogen with CaC2 is ______.
Assertion: Generally alkali and alkaline earth metals form superoxides.
Reason: There is a single bond between O and O in superoxides.
Assertion: BeSO4 is soluble in water while BaSO4 is not
Reason: Hydration energy decreases down the group from Be to Ba and lattice energy remains almost constant.
Beryllium halides are covalent whereas magnesium halides are ionic why?
Alkaline earth metal (A), belongs to 3rd period reacts with oxygen and nitrogen to form compound (B) and (C) respectively. It undergoes metal displacement reaction with AgNO3 solution to form compound (D). Identify A, B, C and D.
Why alkaline earth metals are harder than alkali metals?
The reducing power of a metal depends on various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is ______.
Discuss the trend of the following:
Thermal stability of carbonates of Group 2 elements.
What is the structure of BeCl2 molecule in gaseous and solid state?
Alkaline earth metals show ______.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
Given below are two statements:
Statement I: Colourless cupric metaborate is reduced to cuprous metaborate in a luminous flame.
Statement II: Cuprous metaborate is obtained by heating boric anhydride and copper sulphate in a non-luminous flame.
In the light of the above statements, choose the most appropriate answer from the options given below.
MgBr2 and Mgl2 are soluble in acetone because of ______.
PbCl4 exists but PbBr4 and Pbl4 do not because of ______.
