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Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble?

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प्रश्न

Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble?

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उत्तर

The hydration enthalpies of BeSO4 and MgSO4 are quite high because of small size of Be2+ and Mg2+ ions. These hydration enthalpy values are higher than their corresponding lattice enthalpies and therefore, BeS04 and MgSOare highly soluble in water. However, hydration enthalpies of CaSO4, SrSOand BaSO4 are not very high as compared to their respective lattice enthalpies and hence these are insoluble in water.

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अध्याय 10: The s-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
अध्याय 10 The s-block Elements
Multiple Choice Questions (Type - I) | Q 35 | पृष्ठ १३०

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