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Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble? - Chemistry

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प्रश्न

Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble?

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उत्तर

The hydration enthalpies of BeSO4 and MgSO4 are quite high because of small size of Be2+ and Mg2+ ions. These hydration enthalpy values are higher than their corresponding lattice enthalpies and therefore, BeS04 and MgSOare highly soluble in water. However, hydration enthalpies of CaSO4, SrSOand BaSO4 are not very high as compared to their respective lattice enthalpies and hence these are insoluble in water.

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अध्याय 10: The s-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
अध्याय 10 The s-block Elements
Multiple Choice Questions (Type - I) | Q 35 | पृष्ठ १३०

संबंधित प्रश्न

Discuss the general characteristics and gradation in properties of alkaline earth metals.


Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?


Which one of the alkaline earth metal carbonates is thermally the most stable?


Which of the following has the highest hydration energy


Assertion: Generally alkali and alkaline earth metals form superoxides.

Reason: There is a single bond between O and O in superoxides.


Assertion: BeSO4 is soluble in water while BaSO4 is not

Reason: Hydration energy decreases down the group from Be to Ba and lattice energy remains almost constant.


In context with beryllium, which one of the following statements is incorrect?


Write a balanced chemical equation for the following chemical reaction.

Rubidium with oxygen gas


Beryllium halides are covalent whereas magnesium halides are ionic why?


Alkaline earth metal (A), belongs to 3rd period reacts with oxygen and nitrogen to form compound (B) and (C) respectively. It undergoes metal displacement reaction with AgNO3 solution to form compound (D). Identify A, B, C and D.


Why alkaline earth metals are harder than alkali metals?


Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is ______.


Identify the correct formula of halides of alkaline earth metals from the following.

(i) BaCl2.2H2O

(ii) BaCl2.4H2O

(iii) CaCl2.6H2O

(iv) SrCl2.4H2O


Name an element from Group 2 which forms an amphoteric oxide and a water soluble sulphate.


Discuss the trend of the following:

Thermal stability of carbonates of Group 2 elements.


Discuss the trend of the following:

The solubility and the nature of oxides of Group 2 elements.


Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.


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