Advertisements
Advertisements
प्रश्न
Calculate the half-life of a first order reaction from the rate constant given below:
4 year−1
Advertisements
उत्तर
For a first order reaction,
Half-life (t1/2) = `0.693/k`
= `0.693/4`
= 0.173 years.
संबंधित प्रश्न
Sucrose decomposes in acid solution to give glucose and fructose according to the first order rate law. The half life of the reaction is 3 hours. Calculate fraction of sucrose which will remain after 8 hours.
For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction.
Calculate the half-life of a first order reaction from the rate constant given below:
200 s−1
The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample.
The rate constant for the first order decomposition of H2O2 is given by the following equation:
log k = 14.34 − 1.25 × 104 K/T.
Calculate Ea for this reaction and at what temperature will its half-period be 256 minutes?
The unit of rate constant for zero order reaction is _______.
(A) t–1
(B) mol dm–3 t–1
(C) mol–1 dm3 t–1
(D) mol–2 dm6 t–1
Which among the following reactions is an example of a zero order reaction?
a) `H_(2(g)) + I_(2(g)) -> 2HI_(g)`
b) `2H_2O_(2(l)) -> 2H_2O_(l) + O_(2(g))`
c) `C_12H_22O_(11(aq)) + H_2O_(l) -> C_6H_12O_(6(aq)) + C_6H_12O_(6(aq))`
d) `2NH_(3g)` `N(2g) + 3H_(2(g))`
A first order reaction takes 10 minutes for 25% decomposition. Calculate t1/2 for the reaction.
(Given : log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021)
Show that the time required for 99% completion is double of the time required for the completion of 90% reaction.
The half life period of a first order reaction is 6. 0 h . Calculate the rate constant
In a first-order reaction A → product, 80% of the given sample of compound decomposes in 40 min. What is the half-life period of the reaction?
After 2 hours, a radioactive substance becomes `(1/16)^"th"` of original amount. Then the half life ( in min) is
Define half life of a reaction.
The half life of the homogeneous gaseous reaction \[\ce{SO2Cl2 -> SO2 + Cl2}\] which obeys first order kinetics is 8.0 minutes. How long will it take for the concentration of SO2Cl2 to be reduced to 1% of the initial value?
Which radioactive isotope would have the longer half-life 15O or 19O? (Given rate constants for 15O and 19O are 5.63 × 10–3 s–1 and k = 2.38 × 10–2 s–1 respectively.)
Observe the graph shown in figure and answer the following questions:

Write the relationship between k and t1/2 (half-life period)
For the given first order reaction A → B the half life of the reaction is 0.3010 min. The ratio of the initial concentration of reactant to the concentration of reactant at time 2.0 min will be equal to ______. (Nearest integer)
A reaction has a half-life of 1 min. The time required for 99.9% completion of the reaction is ______ min.
(Round off to the nearest integer).
[Use: In 2 = 0.69; In 10 = 2.3]
The half-lives of a first-order reaction are 1.19s at 313 K and 15.45s at 293 K. Calculate the energy of activation.
