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प्रश्न
Answer the following questions based on the P–T phase diagram of CO2:
Describe qualitatively the changes in a given mass of solid CO2 at 10 atm pressure and temperature –65 °C as it is heated up to room temperature at constant pressure.
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उत्तर १
The fusion and boiling points are given by the intersection point where this parallel line cuts the fusion and vaporisation curves.
Explanation
When the temperature of a mass of solid CO2 (at 10 atm pressure and at –65°C) is increased, it changes to the liquid phase and then to the vaporous phase. It forms a line parallel to the temperature axis at 10 atm. The fusion and boiling points are given by the intersection point where this parallel line cuts the fusion and vaporisation curves.
उत्तर २
When the solid CO2 at – 65 °C is heated at 10 atm pressure, it is first converted into liquid. A further increase in its temperature brings it into the vapour phase. If a horizontal line at P = 10 atm is drawn parallel to the T-axis, then the points of intersection of line with the fusion and vaporization curve give the fusion and boiling points at 10 atm.
संबंधित प्रश्न
Answer the following questions based on the P–T phase diagram of CO2:
CO2 at 1 atm pressure and temperature – 60 °C is compressed isothermally. Does it go through a liquid phase?
Answer the following questions based on the P–T phase diagram of CO2:
What happens when CO2 at 4 atm pressure is cooled from room temperature at constant pressure?
Answer the following questions based on the P–T phase diagram of CO2:
Describe qualitatively the changes in a given mass of solid CO2 at 10 atm pressure and temperature –65 °C as it is heated up to room temperature at constant pressure.
Answer the following questions based on the P–T phase diagram of CO2:
CO2 is heated to a temperature 70 °C and compressed isothermally. What changes in its properties do you expect to observe?
A ‘thermacole’ icebox is a cheap and efficient method for storing small quantities of cooked food in summer in particular. A cubical icebox of side 30 cm has a thickness of 5.0 cm. If 4.0 kg of ice is put in the box, estimate the amount of ice remaining after 6 h. The outside temperature is 45 °C, and coefficient of thermal conductivity of thermacole is 0.01 J s–1 m–1 K–1. [Heat of fusion of water = 335 × 103 J kg–1]
A brass boiler has a base area of 0.15 m2 and thickness 1.0 cm. It boils water at the rate of 6.0 kg/min when placed on a gas stove. Estimate the temperature of the part of the flame in contact with the boiler. The thermal conductivity of brass = 109 J s –1 m–1 K–1; Heat of vaporisation of water = 2256 × 103 J kg–1.
Answer the following question based on the P-T phase diagram of carbon dioxide:
At what temperature and pressure can the solid, liquid and vapour phases of CO2 co-exist in equilibrium?
Mark the correct options:
- A system X is in thermal equilibrium with Y but not with Z. System Y and Z may be in thermal equilibrium with each other.
- A system X is in thermal equilibrium with Y but not with Z. Systems Y and Z are not in thermal equilibrium with each other.
- A system X is neither in thermal equilibrium with Y nor with Z. The systems Y and Z must be in thermal equilibrium with each other.
- A system X is neither in thermal equilibrium with Y nor with Z. The system Y and Z may be in thermal equilibrium with each other.
Latent heat of a substance is best defined as ______.
Relation between heat Q, mass mmm, and specific latent heat L ______.
Effect of increasing external pressure on boiling point ______.
In a heating curve of ice and water, which part represents the latent heat of fusion?
Which statement best explains why the temperature of boiling water remains constant at 100°C until all the water has changed to steam (at 1 atm)?
Why is the latent heat of vaporisation much greater than the latent heat of fusion?
For 1 kg of water, which phase change requires more energy?
