Advertisements
Advertisements
प्रश्न
An ideal gas expands from 100 cm3 to 200 cm3 at a constant pressure of 2.0 × 105 Pa when 50 J of heat is supplied to it. Calculate (a) the change in internal energy of the gas (b) the number of moles in the gas if the initial temperature is 300 K (c) the molar heat capacity Cp at constant pressure and (d) the molar heat capacity Cv at constant volume.
Advertisements
उत्तर
Initial volume of the gas, V1 = 100 cm3
Final volume = V2 = 200 cm3
Pressure = 2 × 105 Pa
Heat supplied, dQ = 50 J
(a) According to the first law of thermodynamics,
dQ = dU + dW
dW = PΔV = 2 × 105 × (200 -100) × 10-6 = 20
Initial volume of the gas, V1 = 100 cm3
Final volume = V2 = 200 cm3
Pressure = 2 × 105 Pa
Heat supplied, dQ = 50 J
(a) According to the first law of thermodynamics,
dQ = dU + dW
`"U" = 3/2 "n""R""T"`
`30 = n xx 3/2 xx 8.3 xx 300`
`=> n = 2/(83 xx3) = 2/249 = 0.008`(c) Also,
dU = nCvdT
`=> "C"_"V" = ("d""U")/ ("n""d""T") = 30 /(0.008 xx 300) = 12.5`
Cp = Cv + R = 12.5 + 8.3 = 20.8 J/mol-K
(d) Cv = 12.5 J/mol-K
APPEARS IN
संबंधित प्रश्न
Given below are densities of some solids and liquids. Give rough estimates of the size of their atoms:
| Substance | Atomic Mass (u) | Density (103 Kg m-3) |
| Carbon (diamond) | 12.01 | 2.22 |
| Gold | 197.00 | 19.32 |
| Nitrogen (liquid) | 14.01 | 1.00 |
| Lithium | 6.94 | 0.53 |
| Fluorine (liquid) | 19.00 | 1.14 |
[Hint: Assume the atoms to be ‘tightly packed’ in a solid or liquid phase, and use the known value of Avogadro’s number. You should, however, not take the actual numbers you obtain for various atomic sizes too literally. Because of the crudeness of the tight packing approximation, the results only indicate that atomic sizes are in the range of a few Å].
The specific heat capacity of water is
Can we define specific heat capacity at constant temperature?
Can a process on an ideal gas be both adiabatic and isothermal?
Show that the slope of the p−V diagram is greater for an adiabatic process compared to an isothermal process.
Can two states of an ideal gas be connected by an isothermal process as well as an adiabatic process?
Two samples A and B are initially kept in the same state. Sample A is expanded through an adiabatic process and the sample B through an isothermal process. The final volumes of the samples are the same. The final pressures in A and B are pA and pBrespectively.
Let ∆Wa and ∆Wb be the work done by the systems A and B, respectively, in the previous question.
A sample of air weighing 1.18 g occupies 1.0 × 103 cm3 when kept at 300 K and 1.0 × 105 Pa. When 2.0 cal of heat is added to it at constant volume, its temperature increases by 1°C. Calculate the amount of heat needed to increase the temperature of air by 1°C at constant pressure if the mechanical equivalent of heat is 4.2 × 107 erg cal−1. Assume that air behaves as an ideal gas.
A mixture contains 1 mole of helium (Cp = 2.5 R, Cv = 1.5 R) and 1 mole of hydrogen (Cp= 3.5 R, Cv = 2.5 R). Calculate the values of Cp, Cv and γ for the mixture.
In Joly's differential steam calorimeter, 3 g of an ideal gas is contained in a rigid closed sphere at 20°C. The sphere is heated by steam at 100°C and it is found that an extra 0.095 g of steam has condensed into water as the temperature of the gas becomes constant. Calculate the specific heat capacity of the gas in J g−1 K−1. The latent heat of vaporisation of water = 540 cal g−1
Air (γ = 1.4) is pumped at 2 atm pressure in a motor tyre at 20°C. If the tyre suddenly bursts, what would be the temperature of the air coming out of the tyre? Neglect any mixing with the atmospheric air.
The speed of sound in hydrogen at 0°C is 1280 m s−1. The density of hydrogen at STP is 0.089 kg m−3. Calculate the molar heat capacities Cp and Cv of hydrogen.
4.0 g of helium occupies 22400 cm3 at STP. The specific heat capacity of helium at constant pressure is 5.0 cal K−1 mol−1. Calculate the speed of sound in helium at STP.
Molar specific heat of water is C = 74.7 J/mol K, its value in cal/g K is ______.
An engine takes in 5 moles of air at 20°C and 1 atm, and compresses it adiabatically to `1/10^"th"` of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is ______.
