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HSC Science (Electronics) 12th Standard Board Exam - Maharashtra State Board Question Bank Solutions

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Define Cryoscopic constant.

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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Draw the structure of: Orthophosphoric acid 

[7.01] Group 15 Elements
Chapter: [7.01] Group 15 Elements
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Describe laboratory method for preparation of glucose.

[14.01] Carbohydrates
Chapter: [14.01] Carbohydrates
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State and explain Markownikoff's rule with suitable example

[10.01] Haloalkanes
Chapter: [10.01] Haloalkanes
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For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction.

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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 A first order reaction takes 40 minutes for 30% decomposition. Calculate t1/2 for this reaction. (Given log 1.428 = 0.1548)

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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In body centred cubic structure the space occupied is about

(A) 68%                                                     (B) 53%

(C) 38%                                                     (D) 32%

[1] Solid State
Chapter: [1] Solid State
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Which of the following solutions shows maximum depression in freezing point?

(A) 0.5 M Li2SQ4

(B) 1 M NaCl

(C) 0.5 M A12(SO4)3

(D) 0.5 MBaC12

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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Draw structure and write geometry of PCl3 and PCl5.

[7.01] Group 15 Elements
Chapter: [7.01] Group 15 Elements
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Prove that ΔH=ΔU+ΔnRT. what is the condition under which ΔU=ΔH?

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
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Prove that ΔH=ΔU+ΔnRT. what is the condition under which ΔU=ΔH?

[3] Chemical Thermodynamics and Energetic
Chapter: [3] Chemical Thermodynamics and Energetic
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How is 4-methylpent-3-en-2-one obtained from propan-2-one?

[12.01] Aldehydes and Ketones
Chapter: [12.01] Aldehydes and Ketones
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Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
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Calculate the amount of CaCl2 (molar mass = 111 g mol−1) which must be added to 500 g of water to lower its freezing point by 2 K, assuming CaCl2 is completely dissociated. (Kf for water = 1.86 K kg mol−1)

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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A first order reaction takes 23.1 minutes for 50% completion. Calculate the time required for 75% completion of this reaction.

(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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Calculate the freezing point of solution when 1.9 g of MgCl2 (M = 95 g mol−1) was dissolved in 50 g of water, assuming MgCl2 undergoes complete ionization.

(Kf for water = 1.86 K kg mol−1)

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate the formula of sulphur (Sx).

(Kf for CS2 = 3.83 K kg mol−1, Atomic mass of sulphur = 32 g mol−1]

[2] Solutions and Colligative Properties
Chapter: [2] Solutions and Colligative Properties
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Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].

(At.no. of Ni = 28)

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
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A first order reaction takes 30 minutes for 50% completion. Calculate the time required for 90% completion of this reaction.

(log 2 = 0.3010)

[6] Chemical Kinetics
Chapter: [6] Chemical Kinetics
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Write the hybridization and shape of the following complexe : [CoF6]3–

(Atomic number : Co = 27, Ni = 28)

[9] Coordination Compounds
Chapter: [9] Coordination Compounds
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