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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions

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For the following reaction:

\[\ce{Fe2O3_{(s)} + 3CO_{(g)} -> 2Fe_{(s)} + 3CO2_{(g)}}\]; ΔH0 = −29.8 kJ and ΔS0 = 15 J K−1. What is the value of \[\ce{ΔS_{(total)}}\] at 298 K?

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Heat of combustion of C(s), H2(g) and C2H6(g) are −x1, −x2 and −x3 respectively. Hence heat of formation of C2H6(g) is ____________.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Which of the following conditions indicates the reaction is spontaneous?

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Equilibrium constant for a reaction is 20. What is the value of ∆G0 at 300 K? (R = 8 × 10−3 kJ)

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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At what temperature, a chemical reaction will have the following values of ∆G, ∆S and ∆H?

∆G = −5.2 KJ mol−1, ∆H = 145.6 kJ mol−1, ∆S = −216 kJ mol−1

[14] Chemical Thermodynamics
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What is the value of effective magnetic moment found in +3 oxidation state of Chromium (Z = 24)?

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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For a reaction to be non-spontaneous at all temperatures, values of ΔH and ΔS respectively are ____________.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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The observed electronic configuration of promethium (atomic number 61) is ____________.

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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In haloalkanes and haloarenes, halogen atom is bonded to ____________ hybridized carbon atom of an alkyl and aryl groups, respectively.

[3] Chemical Bonding
Chapter: [3] Chemical Bonding
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In oxy-acetylene flame for welding and cutting of metals, a mixture of ____________ is used.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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What type of hybridization results in tetrahedral geometry?

[3] Chemical Bonding
Chapter: [3] Chemical Bonding
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Which element from following forms colourless compounds in +2 oxidation state?

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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Identify the correct decreasing order of ionic radii of lanthanoids.

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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Which of the following properties is NOT of lanthanoids?

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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Identify the formula of lanthanoid oxide formed when lanthanoid (Ln) is burnt in oxygen.

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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If ΔH° and ΔS° for the reaction \[\ce{N2O_{4(g)} -> 2NO_{2(g)}}\] is 57.24 kJ and 175.8 JK-1 mol-1 respectively. What is the value of ΔG° for this reaction at 298 K?

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Which of following is residual entropy of a substance?

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Standard molar entropy is ______.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Calculate the amount of heat liberated during formation of 2. 7 kg of water if heat of formation of water is - 284.5 kJ mol-1.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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The H-H bond energy is 430 kJ mol-1 and Cl-Cl bond energy is 240 kJ mol-1. ΔfH for HCl is - 90 kJ, then H-Cl bond energy is ______.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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