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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions

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The standard electrode potential (E0) values of Al3+/Al, Au3+/Au and Pb2+/Pb are −1.66 V, 1.50 V and −0.126 V, respectively. The CORRECT increasing order of reducing power of the metal is:

[4] Redox Reactions
Chapter: [4] Redox Reactions
Concept: undefined >> undefined

Identify 'A' and 'B' in the following series of reactions.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

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A system absorbs 900 J of heat and does work. The change in internal energy (∆U) for the process is +460 J. The work done by the system is ____________.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
Concept: undefined >> undefined

\[\ce{CH3 - CH = CH2 ->[HBr][Peroxide] A}\]

Identify A.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

The product 'C' in the following reaction is:

\[\ce{CH3CH2Br ->[alc. KCN] {'A'} ->[H3O^+][\Delta] {'B'} ->[i. LiAlH4][ii. H3O^+] {'C'}}\]

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

\[\ce{CH3-CN ->[Na/C2H5OH]}\]

The product formed is ____________.

[23] Amines
Chapter: [23] Amines
Concept: undefined >> undefined

Which of the following is INCORRECT?

[12] Solutions
Chapter: [12] Solutions
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The following reaction is known as:

\[\ce{R - Cl + NaI ->[acetone] R - I + NaCl ↓}\]

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
Concept: undefined >> undefined

If a metal crystallises in bcc structure with edge length of unit cell 4.29 × 10-8 cm the radius of metal atom is ______.

[11] Solid State
Chapter: [11] Solid State
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Carbolic acid is oxidised by acidified sodium dichromate to give ______.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

For the elementary reaction, \[\ce{3H2_{(g)} + N2_{(g)} -> 2NH3_{(g)}}\] identify the correct relation among the following relations.

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
Concept: undefined >> undefined

If the heat of formation of HCl is 92.5 kcal, what is the heat of formation of 73 g HCl?

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
Concept: undefined >> undefined

Which nitrogen containing compound amongst the following would undergo Mendius reduction to furnish primary amine \[\ce{(R - NH2)}\]?

[23] Amines
Chapter: [23] Amines
Concept: undefined >> undefined

In Dow process, chlorobenzene is converted into phenol by ____________.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

+I effect of alkyl groups in alcohols increases the stability of ____________.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

If the standard electrode potential of Cu2+/Cu electrode is 0.34 V, what is the electrode potential if concentration of Cu2+ ions is 0.01 M (T = 298 K)?

[4] Redox Reactions
Chapter: [4] Redox Reactions
Concept: undefined >> undefined

Adsorption of a gas follows Freundlich adsorption isotherm. x is the mass of the gas adsorbed on mass m of the adsorbent. The plot of log `"x"/"m"`· versus log P is shown in the given m graph. `"x"/"m"` is proportional to

[7] Adsorption and Colloids
Chapter: [7] Adsorption and Colloids
Concept: undefined >> undefined

The CORRECT relationship between heat of fusion (∆fusH), heat of vapourization (∆vapH) and heat of sublimation (∆subH) is ____________.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
Concept: undefined >> undefined

____________ will NOT undergo acetylation.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

Which of the following reactions is appropriate for converting benzamide to aniline?

[23] Amines
Chapter: [23] Amines
Concept: undefined >> undefined
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