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JEE Main entrance exam Question Bank Solutions for Chemistry (JEE Main)

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Chemistry (JEE Main)
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The correct order of the spin-only magnetic moment of metal ions in the following low spin complexes,

\[\ce{[V(CN)6]^{4-}, [Fe(CN)6]^{4-}, [Ru(NH3)6]^{3+} and [Cr(NH3)6]^2}\] is:

[17] Co-ordination Compounds
Chapter: [17] Co-ordination Compounds
Concept: undefined >> undefined

The major Product of the following reaction is:

[11] Classification of Elements and Periodicity in Properties
Chapter: [11] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

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A drop of solution (volume 0.05 ml) contains 3.0 × 10-6 mole of H+. If the rate constant of disappearance of H+ is 1.0 × 107 mole l-1s-1. It would take for H+ in drop to disappear in ______ × 10-9s.

[9] Chemical Kinetics
Chapter: [9] Chemical Kinetics
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For a chemical reaction starting with some initial concentration of reactant At as a function of time (t) is given by the equation,

`1/("A"_"t"^4) = 2 + 1.5 xx 10^-3` t

The rate of disappearance of [A] is ____ × 10-2 M/sec when [A] = 2 M.

[Given: [At] in M and t in sec.]
[Express your answer in terms of 10-2 M /s]
[Round off your answer if required]

[9] Chemical Kinetics
Chapter: [9] Chemical Kinetics
Concept: undefined >> undefined

A strong current of trivalent gaseous boron passed through a silicon crystal decreases the density of the crystal due to part replacement of silicon by boron and due to interstitial vacancies created by missing Si atoms. In one such experiment, one gram of silicon is taken and the boron atoms are found to be 1000 ppm by weight, when the density of the Si crystal decreases by 12%. The percentage of missing vacancies due to silicon, which are filled up by boron atoms will be ____ g. [Given · Atomic wt. Si= 30, B = 11]

[2] States of Matter
Chapter: [2] States of Matter
Concept: undefined >> undefined

Consider an isothermal cylinder and massless piston assembly in which ideal gas is filled. Cross-sectional area of the cylinder = 1 m2. Three masses m1, m2 and m3 are kept on the piston. When m1 is removed, the piston moves upto point A. When m1 and m2 both are removed piston moves upto point B and when m1, m2 and m3 all three are removed, piston moves upto point C. The work done by the gas is ______ J, when piston moves from point B to point C.

[Given : m1 = 2 × 104 kg, m2 = 3 × 104 kg, g = 10 m/s2]

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
Concept: undefined >> undefined

The density of solid Argon is 1.6 ml at - 233°C. If the Argon atom is assumed to be sphere of radius 1.5 × 10-8 cm, then the ______ % of solid Argon is apparently occupied.

[Take : NA = 6 × 1023, Atomic mass of Ar = 40]

[2] States of Matter
Chapter: [2] States of Matter
Concept: undefined >> undefined

On small scale, boron is best isolated by reducing boron trioxide with ______.

[15] P-block Elements
Chapter: [15] P-block Elements
Concept: undefined >> undefined

A given solution of H2O2 is 30 volumes. Its concentration in terms of molarity is ______.

[6] Solutions
Chapter: [6] Solutions
Concept: undefined >> undefined

Glycinato ligand is ______.

[17] Co-ordination Compounds
Chapter: [17] Co-ordination Compounds
Concept: undefined >> undefined

The composition of a sample of wustite is Fe0.93O1.0· The iron is present in the form of Fe(III) is ______%.

[2] States of Matter
Chapter: [2] States of Matter
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A sample of Ferrous sulphide reacts with dil. H2SO4 to from H2S which contains 9% hydrogen by volume. The percentage of fee in the sample, is ______.

[6] Solutions
Chapter: [6] Solutions
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The molarity of the solution prepared by dissolving 6.3 g of oxalic acid (H2C2O4 · 2 H2O) in 250 mL of water in mol L-1 is x × 10-2. The value of x is ______. (Nearest integer)

[Atomic mass: H : 1.0, C : 12.0, O : 16.0]

[6] Solutions
Chapter: [6] Solutions
Concept: undefined >> undefined

The mole fraction of a solute in a 100 molal aqueous solution is ______ × 10-2. (Round off to the Nearest Integer).

[Given :Atomic masses : H : 1.0 u, O : 16.0 u]

[6] Solutions
Chapter: [6] Solutions
Concept: undefined >> undefined

A flask contains a mixture of compounds A and B. Both compounds decompose by first-order kinetics. The half-lives for A and B are 300 s and 180 s, respectively. If the concentrations of A and B are equal initially, the time required for the concentration of A to be four times that of B (in s) is ______. (Use ln 2 = 0.693)

[9] Chemical Kinetics
Chapter: [9] Chemical Kinetics
Concept: undefined >> undefined

Match List - I with List - II.

  List - I   List - II
  (One)   (Composition)
(A) Siderite (I) FeCO3
(B) Malachite (II) CuCO3 · Cu(OH)2
(C) Sphalerite (III) ZnS
(D) Calamine (IV) ZnCO3

Choose the correct answer from the options given below:

[12] General Principles and Processes of Isolation of Metals
Chapter: [12] General Principles and Processes of Isolation of Metals
Concept: undefined >> undefined

Calamine and Malachite, respectively, are the ores of ______.

[12] General Principles and Processes of Isolation of Metals
Chapter: [12] General Principles and Processes of Isolation of Metals
Concept: undefined >> undefined

The ore that contains both iron and copper is ______.

[12] General Principles and Processes of Isolation of Metals
Chapter: [12] General Principles and Processes of Isolation of Metals
Concept: undefined >> undefined

4 ml of pure A (d = 2.45 gm/ml) was added to 46 ml of B (d = `25.1/23` gm/ml), the molarity of a solution of A in B will be ______, if the density of the final solution is 1.8 gm/ml.

Given: Molar mass of A = 98, Molar mass of B = 46

[6] Solutions
Chapter: [6] Solutions
Concept: undefined >> undefined

The group number, number of valence electrons, and valency of an element with atomic number 15, respectively, are ______.

[11] Classification of Elements and Periodicity in Properties
Chapter: [11] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined
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