Advertisements
Advertisements
To synthesise 1.0 mole of 2-methylpropan-2-ol from Ethylethanoate ______ equivalents of CH3MgBr reagent will be required. (Integer value)
Concept: undefined >> undefined


The products "A" and "B" formed in above reactions are:
Concept: undefined >> undefined
Advertisements
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
Concept: undefined >> undefined
An aldehyde isomeric with allyl alcohol gives phenyl hydrazone. Pick out a ketone that too gives a phenyl hydrazone containing the same percentage of nitrogen.
Concept: undefined >> undefined
\[\ce{C3H8O ->[{[O]}][K2Cr2O7/H2SO4] C3H6O ->[I2 + NaOH(aq.)] CHI3}\]
In this reaction the first compound is:
Concept: undefined >> undefined
\[\ce{H2O2 -> H2O + O2}\]
This represents ______.
Concept: undefined >> undefined
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
Concept: undefined >> undefined
The lathanide ion that would show colour is ______.
Concept: undefined >> undefined
Which of the following compound is optically active?
Concept: undefined >> undefined
Glucose with excess of phenyl hydrazine forms ______.
Concept: undefined >> undefined
In an experiment O3 undergo decomposition as \[\ce{O3 -> O2 + O}\] by the radiations of wavelength 310 Å. The total energy falling on the O3 gas molecules is 2.4 × 1026 eV and quantum yield of the reaction is 0.2.
The volume strength of the H2O2 solution which is obtained from reaction of 1 l H2O and nascent oxygen [O] obtained from the above reactions is (Assuming no change in volume of H2O)
\[\ce{H2O + O -> H2O2}\]
[Given: Na (Avogadro's No.) = 6 × 1023]
Concept: undefined >> undefined
For distinction between \[\ce{CH3CHO}\] and \[\ce{C6H5CHO}\] the reagent used is ______.
Concept: undefined >> undefined
For the decomposition reaction \[\ce{NH2COONH4 (s) <=> 2NH3 (g) + CO2 (g)}\] the Kp = 2.9 × 10-5 atm3. The total pressure of gases at equilibrium when 1 mol of \[\ce{NH2COONH4 (s)}\] was taken initially could be ______.
Concept: undefined >> undefined
\[\ce{SiCl4 ->[H2O] (A) ->[\Delta] (B) ->[Na2CO3][heat] (C)}\]. The Compound C is ______.
Concept: undefined >> undefined
Which of the following compound cannot be produced if 1-propane amine is treated with NaNO2 and HCl?
Concept: undefined >> undefined
Which compound would exhibit optical isomers?
Concept: undefined >> undefined
The number of geometrical isomers of \[\ce{[Co(NH3)3 (NO3)3]}\] are ______.
Concept: undefined >> undefined
\[\ce{? ->[\Delta, CN-][EtOH, H2O]}\] Benzoin.
The reactant is obtained by dry distillation of the calcium salts of the following pairs:
Concept: undefined >> undefined
If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that dissolve in 1 litre of water is ______. (Nearest integer)
(Given: Henry's Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920 bar)
(Assume solubility of O2 in water is too small, nearly negligible)
Concept: undefined >> undefined
Henry's constant (in k bar) for four gases α, β, γ and δ in water at 298 K is given below:
| α | β | γ | δ | |
| KH | 50 | 2 | 2 × 10-5 | 0.5 |
(density of water = 103 kg m-3 at 298 K)
This table implies that:
Concept: undefined >> undefined
