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Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]
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Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3CH2C(CH3)2CH2I}\]
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Write the structure of the following compound:
1,4-Dibromobut-2-ene
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Give the IUPAC name of the following compound:
\[\ce{(CCl3)3CCl}\]
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What are interstitial compounds?
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Write the differences between physisorption and chemisorption with respect to the following:
(i) Specificity
(ii) Temperature dependence
(iii) Reversibility and
(iv) Enthalpy change
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Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?
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Which of the following cations are coloured in aqueous solutions and why ?
Sc3+, V3+, Ti4+, Mn2+ (At. Nos. Sc = 21, V = 23, Ti = 22, Mn = 25)
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How would you account for the following?
Transition metals exhibit variable oxidation states.
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Complete the following chemical equations:
`(i) Cr_2O_7^(2-)+6Fe^(2+)+14H^+ ->`
`(ii) 2CrO_4^(2-)+2H^+ ->`
`(iii) 2MnO_4^-+5C_2O_4^(2-)+16H^+ ->`
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Pb(NO3)2 on heating gives a brown gas which undergoes dimerisation on cooling? Identify the gas
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Account for the following:
Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.
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Account for the following:
Cr2+ is a strong reducing agent.
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Account for the following:
Cu+2 salts are coloured, while Zn2+ salts are white.
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The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co
Answer the following: Write the element which shows maximum number of oxidation states. Give reason.
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The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co
Answer the following: Which element has the highest m.p?
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The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co
Answer the following: Which element shows only +3 oxidation state?
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The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co
Answer the following: Which element is a strong oxidising agent in +3 oxidation state and why?
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Why do the transition elements have higher enthalpies of atomisation?
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In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?
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