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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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 Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :

On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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\[C_6 H_5 - OH \to^{{Br}_2 \left( aq \right)} ?\]
[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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An element X (molar mass = 60 g mol−1) has a density of 6.23 g cm−3. Identify the type of cubic unit cell, if the edge length of the unit cell is 4 ✕ 10−8 cm.

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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Account for the following :

Reducing character decreases from SO2 to TeO2.

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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Define an ideal solution and write one of its characteristics.

[1] Solutions
Chapter: [1] Solutions
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After the ban on plastic bags, students of a school decided to make people aware of the harmful effects of plastic bags on the environment and Yamuna River. To make the awareness more impactful, they organised a rally by partnering with other schools and distributed paper bags to vegetable vendors, shopkeepers and departmental stores. All the students pledged not to use polythene bags in the future to save the Yamuna River.

After reading the above passage, answer the following questions:
(i) What values are shown by the students?
(ii) What are bio-degradable polymers? Give one example.
(iii) Is polythene a condensation or an addition polymer?

[15] Polymers
Chapter: [15] Polymers
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Arrange the following in the order of the property indicated against set :
H2O, H2S, H2Se, H2Te − increasing acidic character.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Write the product formed on reaction of D-glucose with Br2 water.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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What type of intermolecular attractive interaction exists in the pair of methanol and acetone?

[1] Solutions
Chapter: [1] Solutions
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Define disinfectants with a Suitable example?

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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What are anionic detergents? Give an example ?

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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 Account for the following: 
On reaction with benzene sulphonyl chloride, primary amine yields product soluble in alkali whereas secondary amine yields product insoluble in alkali.

[9] Amines
Chapter: [9] Amines
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 What is the role of promoters and poisons in catalysis?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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 Give reactions for the following: 
O – O single bond is weaker than S – S single bond. 

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Define the following term with a suitable example: 
Cationic detergents

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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Write chemical equation in support of your answer. 
 Out of  Cl and O2N Cl. which one is more reactive  towards nucleophilic substitution reaction and why?

[9] Amines
Chapter: [9] Amines
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[NiCl4]2- is paramagnetic while [Ni(CO)4] is  diamagnetic though both are tetrahedral. Why? (Atomic no. Ni = 28) 

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Arrange the following in order of the property indicated set.
HF, HCl, HBr, HI - decreasing bond enthalpy.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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What type of detergents are used in toothpaste? 

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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