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Science (English Medium) Class 11 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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The fragrance of flowers is due to the presence of some steam volatile organic compounds called essential oils. These are generally insoluble in water at room temperature but are miscible with water vapour in vapour phase. A suitable method for the extraction of these oils from the flowers is ______.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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If a liquid compound decomposes at its boiling point, which method (s) can you choose for its purification. It is known that the compound is stable at low pressure, steam volatile and insoluble in water.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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By mistake, an alcohol (boiling point 97°C) was mixed with a hydrocarbon (boiling point 68°C). Suggest a suitable method to separate the two compounds. Explain the reason for your choice.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Assertion (A): Components of a mixture of red and blue inks can be separated by distributing the components between stationary and mobile phases in paper chromatography.

Reason (R): The coloured components of inks migrate at different rates because paper selectively retains different components according to the difference in their partition between the two phases.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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You have a mixture of three liquids A, B and C. There is a large difference in the boiling points of A and rest of the two liquids i.e., B and C. Boiling point of liquids B and C are quite close. Liquid A boils at a higher temperature than B and C and boiling point of B is lower than C. How will you separate the components of the mixture. Draw a diagram showing set up of the apparatus for the process.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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A liquid with high boiling point decomposes on simple distillation but it can be steam distilled for its purification. Explain how is it possible?

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Despite their - I effect, halogens are o- and p-directing in haloarenes. Explain.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Suggest a route to prepare ethyl hydrogensulphate (CH3 – CH2 – OSO2 – OH) starting from ethanol (C2H5OH).

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction,

\[\ce{CaCO_{3(s)} + 2 HCl_{(aq)} → CaCl_{2(aq)} + CO_{2(g)} + H2O_{(l)}}\]

What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with aqueous hydrochloric acid according to the reaction

\[\ce{4HCl_{(aq)} + MnO_{2(s)} → 2H2O_{(l)} + MnCl_{2(aq)} + Cl_{2(g)}}\]

How many grams of HCl react with 5.0 g of manganese dioxide?

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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Symbols `""_35^79"Br"` and `""^79"Br"` can be written, whereas symbols `""_79^35"Br"` and `""^35"Br"` are not acceptable. Answer briefly.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. If any of these combination(s) has/have the same energy lists:

  1. n = 4, l = 2, ml = –2 , ms = - 1/2
  2. n = 3, l = 2, ml= 1 , ms = +1/2
  3. n = 4, l = 1, ml = 0 , ms = +1/2
  4. n = 3, l = 2, ml = –2 , ms = –1/2
  5. n = 3, l = 1, ml = –1 , ms= +1/2
  6. n = 4, l = 1, ml = 0 , ms = +1/2
[2] Structure of Atom
Chapter: [2] Structure of Atom
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How many sub-shells are associated with n = 4?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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How many electrons will be present in the sub-shells having ms value of - 1/2 for n = 4?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
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Explain the physical significance of Van der Waals parameters.

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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Knowing the properties of H2O and D2O, do you think that D2O can be used for drinking purposes?

[9] Hydrogen
Chapter: [9] Hydrogen
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Match the species in Column I with the geometry/shape in Column II.

Column I Column II
(i) \[\ce{H3O+}\] (a) Linear
(ii) \[\ce{HC ≡ CH}\] (b) Angular
(iii) \[\ce{ClO^{-}2}\] (c) Tetrahedral
(iv) \[\ce{NH^{+}4}\] (d) Trigonal bipyramidal
  (e) Pyramidal
[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
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What is \[\ce{SI}\] unit of viscosity coefficient (η)?

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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