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Science (English Medium) Class 11 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Match the ions given in Column I with their nature given in Column II.

Column I Column II
(i) \[\ce{CH3 - \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - \overset{⊕}{C}H - CH3}\] (a) Stable due to resonance
(ii) \[\ce{F3 - \overset{⊕}{C}}\]  (b) Destabilised due to inductive effect

(iii) \[\begin{array}{cc}
\phantom{........}\ce{CH3}\\
\phantom{......}|\\
\ce{CH3 - C^Θ}\\
\phantom{......}|\\
\phantom{........}\ce{CH3}
\end{array}\]

(c) Stabilised by hyperconjugation
(iv) \[\ce{CH3 - \overset{⊕}{C}H - CH3}\] (d) A secondary carbocation
[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Arrange the halogens F2, Cl2, Br2, I2, in order of their increasing reactivity with alkanes.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

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The addition of HBr to 1-butene gives a mixture of products A, B and C

(A)
(B)
(C) CH3 – CH2 – CH2 – CH2 – Br

The mixture consists of:

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Arrange the following hydrogen halides in order of their decreasing reactivity with propene.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Which of the following alkenes on ozonolysis give a mixture of ketones only?

(i) CH3 – CH = CH – CH3
(ii) \[\begin{array}{cc}
\ce{CH3 - C - CH = CH2}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii)
(iv) \[\begin{array}{cc}
\phantom{...................}\ce{CH3}\\
\phantom{..............}/\\
\ce{(CH3)2 C = C}\\
\phantom{..............}\backslash\\
\phantom{...................}\ce{CH3}
\end{array}\]
[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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In the presence of peroxide addition of HBr to propene takes place according to anti Markovnikov’s rule but peroxide effect is not seen in the case of HCl and HI. Explain.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of ‘A’.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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An alkene ‘A’ contains three C-C, eight C-H σ bonds and one C-C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of ‘A’.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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What is the basic difference between the terms electron gain enthalpy and electronegativity?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number (`bar v`) of the yellow light.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Find energy of each of the photons which correspond to light of frequency 3 × 1015 Hz.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Find energy of each of the photons which have the wavelength of 0.50 Å.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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What is the number of photons of light with a wavelength of 4000 pm that provide 1 J of energy?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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A photon of wavelength 4 × 10–7 m strikes on the metal surface, the work function of the metal being 2.13 eV. Calculate

  1. the energy of the photon (eV),
  2. the kinetic energy of the emission, and
  3. the velocity of the photoelectron (1 eV = 1.6020 × 10–19 J).
[2] Structure of Atom
Chapter: [2] Structure of Atom
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A 25-watt bulb emits monochromatic yellow light of the wavelength of 0.57μm. Calculate the rate of emission of quanta per second.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Electrons are emitted with zero velocity from a metal surface when it is exposed to radiation of wavelength 6800 Å. Calculate threshold frequency (v0) and work function (W0) of the metal.

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Following results are observed when sodium metal is irradiated with different wavelengths. Calculate (a) threshold wavelength and, (b) Planck’s constant.

λ (nm) 500 450 400
v × 10-5 (cm s-1) 2.55 4.35 5.35
[2] Structure of Atom
Chapter: [2] Structure of Atom
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The electron energy in the hydrogen atom is given by En = (–2.18 × 10–18)/n2 J. Calculate the energy required to remove an electron completely from the n = 2 orbit. What is the longest wavelength of light in cm that can be used to cause this transition?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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In astronomical observations, signals observed from the distant stars are generally weak. If the photon detector receives a total of 3.15 × 10–18 J from the radiations of 600 nm, calculate the number of photons received by the detector.

[2] Structure of Atom
Chapter: [2] Structure of Atom
Concept: undefined >> undefined
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