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How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
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What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?
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The first ionization enthalpy values (in kJmol–1) of group 13 elements are:-
| B | Al | Ga | In | Tl |
| 801 | 577 | 579 | 558 | 589 |
How would you explain this deviation from the general trend?
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Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer.
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Which one of the following statements is incorrect in relation to ionization enthalpy?
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Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10-10s.
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Arrange the following type of radiations in increasing order of frequency:
- radiation from microwave oven
- amber light from traffic signal
- radiation from FM radio
- cosmic rays from outer space and
- X-rays.
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Nitrogen laser produces radiation at a wavelength of 337.1 nm. If the number of photons emitted is 5.6 × 1024, calculate the power of this laser.
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Neon gas is generally used in the signboards. If it emits strongly at 616 nm, calculate
- the frequency of emission,
- distance traveled by this radiation in 30 s
- energy of quantum and
- number of quanta present if it produces 2 J of energy.
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Although both CO2 and H2O are triatomic molecules, the shape of H2O molecule is bent while that of CO2 is linear. Explain this on the basis of dipole moment.
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Write the significance/applications of dipole moment.
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Define electronegativity.
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How does electronegativity differ from electron gain enthalpy?
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Explain with the help of suitable example polar covalent bond.
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Arrange the bonds in order of increasing ionic character in the molecules: LiF, K2O, N2, SO2 and ClF3.
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Which out of NH3 and NF3 has higher dipole moment and why?
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At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
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The pressure of 1 g of an ideal gas A at 27 °C is found to be 2 bar. When 2 g of another ideal gas B is introduced in the same flask at the same temperature the pressure becomes 3 bar. Find a relationship between their molecular masses.
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The drain cleaner, Drainex contains small bits of aluminum which react with caustic soda to produce dihydrogen. What volume of dihydrogen at 20 °C and one bar will be released when 0.15g of aluminum reacts?
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The density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
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