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Science (English Medium) Class 11 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Fluorine reacts with ice and results in the change: \[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Justify that this reaction is a redox reaction.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

[7] Redox Reactions
Chapter: [7] Redox Reactions
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How do you count for the following observations?

When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Consider the reactions:

\[\ce{2S_2O_3^{(2-)}(aq) + l_2(S) -> S_4O_6^{(2-)}(aq) + 2l-(aq)}\]

\[\ce{S_2O_3^{(2-)}(aq) + 2Br_2(l) + 5H_2O(l) -> 2SO_4^{2-} (aq) + 4Br-(aq) + 10H+ (aq)}\]

Why does the same reductant, thiosulphate react differently with iodine and bromine?

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Why does the following reaction occur?

\[\ce{XeO^{4-}_6 (aq) + 2F- (aq) + 6H+ (aq) -> XeO3(g) + F_2(g) + 3H_2O(l)}\]

What conclusion about the compound Na4XeO6 (of which `"XeO"_6^(4+)` is a part) can be drawn from the reaction.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?

[7] Redox Reactions
Chapter: [7] Redox Reactions
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What sorts of informations can you draw from the following reaction ?

\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Refer to the periodic table given in your book and now answer the following questions:

Select the possible non-metals that can show disproportionation reaction.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Refer to the periodic table given in your book and now answer the following question:

Select three metals that can show disproportionation reaction.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Arrange the following metals in the order in which they displace each other from the solution of their salts.

Al, Cu, Fe, Mg and Zn.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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What is the minimum volume of water required to dissolve 1g of calcium sulphate at 298 K? (For calcium sulphate, Ksp is 9.1 × 10–6).

[6] Equilibrium
Chapter: [6] Equilibrium
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A measured temperature on Fahrenheit scale is 200 °F. What will this reading be on Celsius scale?

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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The density of 3 molal solution of \[\ce{NaOH}\] is 1.110 g mL–1. Calculate the molarity of the solution.

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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Volume of a solution changes with change in temperature, then, will the molality of the solution be affected by temperature? Give reason for your answer.

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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