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Explain the following term:
Substitutional impurity defect
Concept: Crystal Defects or Imperfections
Explain the following term:
Interstitial impurity defect
Concept: Crystal Defects or Imperfections
Silver crystallizes in the fcc structure. If the edge length of the unit cell is 400 pm, calculate the density of silver (Atomic mass of Ag = 108).
Concept: Cubic System
The number of particles present in Face Centred Cubic Unit cell is/are ______.
Concept: Cubic System
Predict the type of cubic lattice of a solid element having edge length of 400 pm and density is 6.25 g/ml.
(Atomic mass of element = 60)
Concept: Packing of Particles in Crystal Lattice
Write the formula to determine the molar mass of a solute using freezing point depresssion method.
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
Why is molality of a solution independent of temperature?
Concept: Expressing Concentration of Solutions
1.0 x10-3Kg of urea when dissolved in 0.0985 Kg of a solvent, decreases freezing point of the solvent by 0.211 k. 1.6x10 Kg of another non-electrolyte solute when dissolved in 0.086 Kg of the same solvent depresses the freezing point by 0.34 K. Calculate the molar mass of the another solute. (Given molar mass of urea = 60)
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
The substance ‘X’, when dissolved in solvent water gave molar mass corresponding to the molecular formula ‘X3’. The van’t Hoff factor (i) is _______.
(A) 3
(B) 0.33
(C) 1.3
(D) 1
Concept: Abnormal Molar Masses
The boiling point of water at high altitude is low. because________________ .
(a) the temperature is low.
(b) the atmospheric pressure is low.
(c) the temperature is high.
(d) the atmospheric pressure is high
Concept: Solubility >> Solubility of a Solid in a Liquid
Define Cryoscopic constant.
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Which of the following solutions shows maximum depression in freezing point?
(A) 0.5 M Li2SQ4
(B) 1 M NaCl
(C) 0.5 M A12(SO4)3
(D) 0.5 MBaC12
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
Explain, why do aquatic animals prefer to stay at lower level of water during summer?
Concept: Solubility >> Solubility of a Gas in a Liquid
Which of the following is not a colligative property?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Which of the following is not a colligative property?
Concept: Colligative Properties and Determination of Molar Mass >> Osmosis and Osmotic Pressure
Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of KH (Henry’s constant) and why
Concept: Solubility >> Solubility of a Gas in a Liquid
Why do gases always tend to be less soluble in liquids as the temperature is raised?
Concept: Solubility >> Solubility of a Gas in a Liquid
Calculate the amount of CaCl2 (molar mass = 111 g mol−1) which must be added to 500 g of water to lower its freezing point by 2 K, assuming CaCl2 is completely dissociated. (Kf for water = 1.86 K kg mol−1)
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
