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5 moles of helium expand isothermally and reversibly from a pressure 40 × 10-5 N m-2 to 4 × 10-5 N m-2 at 300 K. Calculate the work done, change in internal energy and heat absorbed during the expansion. (R = 8.314 J K-1 mol-1).
Concept: Chemical Thermodynamics and Energetic >> Work, Heat, Energy, Extensive and Intensive Properties
Write features of a reversible process.
Concept: Chemical Thermodynamics and Energetic >> Chemical Thermodynamics and Energetic
A substance which shows the highest entropy is ___________.
Concept: Chemical Thermodynamics and Energetic >> Dilution Introduction of Entropy as a State Function
Choose the most correct answer:
Which of the Na following is a buffer solution?
Concept: Buffer Solutions
Choose the most correct answer :
For pH > 7 the hydronium ion concentration would be _________.
Concept: The pH Scale
Answer the following in brief :
What are acids and bases according to Arrhenius theory?
Concept: Acids and Bases in Daily Life
In NaOH solution [OH–] is 2.87 × 10–4. Calculate the pH of the solution.
Concept: The pH Scale
Answer the following :
Explain the relation between ionic product and solubility product to predict whether a precipitate will form when two solutions are mixed?
Concept: Solubility Product >> Solubility product
For a reaction \[\ce{HCl_{(aq)} + H2O_{(l)} ⇌ H3O^+_{ (aq)} + Cl^-_{ (aq)}}\]
Which of the following is a conjugate acid-base pair?
Concept: Acids and Bases in Daily Life
The theory which explain amphoteric nature of water is ______.
Concept: Acids and Bases in Daily Life
The pKb of weak base BOH [Kb(BOH) = 1 × 10-5] will be ______.
Concept: Buffer Solutions
The solubility product of BaCl2 is 4.0 × 10-8. What will be its molar solubility in mol dm-3?
Concept: Solubility Product >> Solubility product
Classify the following species into Lewis acids and Lewis bases.
| Cl- | |
| `"NH"_4^+` | |
| BCl3 | |
| NH3 |
Concept: Acids and Bases in Daily Life
Explain the types of buffer solutions.
Concept: Buffer Solutions
Derive the equation which implies that the degree of dissociation of weak acid is inversely proportional to the square root of its concentration.
Concept: Types of Electrolyte
A buffer solution contains 0.3 mol dm–3 NH4OH (Kb = 1.8 × 10–5) and 0.4 mol dm–3 NH4Cl. Calculate pOH of the solution.
Concept: Buffer Solutions
The solubility of AgBr in water is 1.20 × 10–5 mol dm–3. Calculate the solubility product of AgBr.
Concept: Solubility Product >> Solubility product
Distinguish between strong electrolyte and weak electrolyte.
Concept: Types of Electrolyte
The pH of 0.001 M HCl solution is ______.
Concept: The pH Scale
