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Question
Write the relative rate expressions for the following chemical reaction:
\[\ce{4NH3_{(g)} + 5O2_{(g)} -> 4NO_{(g)} + 6H2O_{(g)}}\]
Numerical
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Solution
For the reaction \[\ce{4NH3_{(g)} + 5O2_{(g)} -> 4NO_{(g)} + 6H2O_{(g)}}\]
Relative rate expressions are written by dividing the rate of change of concentration of each species by its stoichiometric coefficient.
Rate = \[\ce{\frac{1}{4} \frac{d[NH_3]}{dt}}\]
Rate = \[\ce{\frac{1}{5} \frac{d[O_2]}{dt}}\]
Rate = \[\ce{\frac{1}{4} \frac{d[NO_2]}{dt}}\]
Rate = \[\ce{\frac{1}{6} \frac{d[H_2O]}{dt}}\]
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Chapter 4: Chemical Kinetics - REVIEW EXERCISES [Page 231]
