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Question
Write an example of a neutral molecule which is isoelectronic to ClO−.
Long Answer
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Solution
- The species ClO− has 26 electrons in total (17 from Cl, 8 from O, plus 1 extra electron).
- A neutral molecule that is isoelectronic with ClO− must also have 26 electrons.
- ClF (chlorine monofluoride) is a neutral molecule with 17 electrons from Cl and 9 from F, totalling 26 electrons.
- Thus, ClF is isoelectronic to ClO−.
- ClF acts as a Lewis base because the chlorine atom has lone pairs available for bonding.
Therefore, an example of a neutral molecule isoelectronic to ClO− is ClF.
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