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Question
Why is the Cu+ ion colourless?
Short Answer
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Solution
- Cu+ ions have a completely filled d-orbital configuration (3d10).
- Because all d-orbitals are fully occupied, no electrons are available for d-d electronic transitions.
- d-d transitions are responsible for colour in transition metal ions, caused by absorption of visible light.
- Without such transitions, Cu+ ions do not absorb visible light and thus appear colourless.
- Similarly, ions like Zn2+ and Cd2+ with filled d-orbitals are also colourless.
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