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Why is the Cu+ ion colourless? - Chemistry (Theory)

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Question

Why is the Cu+ ion colourless?

Short Answer
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Solution

  1. Cu+ ions have a completely filled d-orbital configuration (3d10).
  2. Because all d-orbitals are fully occupied, no electrons are available for d-d electronic transitions.
  3. d-d transitions are responsible for colour in transition metal ions, caused by absorption of visible light.
  4. Without such transitions, Cu+ ions do not absorb visible light and thus appear colourless.
  5. Similarly, ions like Zn2+ and Cd2+ with filled d-orbitals are also colourless.
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