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Tamil Nadu Board of Secondary EducationHSC Science Class 12

Why europium (II) is more stable than Cerium (II)?

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Question

Why europium (II) is more stable than Cerium (II)?

Answer in Brief
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Solution

Eu (Z = 63)

Electronic configuration – [Xe] 4f7 5d0 6s2

Eu2+ – Electronic configuration Electronic 6s1

Ce (Z = 58)

Electronic configuration – [Xe] 4f2+ 5d0 6s2+

Ce2+ – Electronic confluration – [Xe] 4f2 5d0

According to the Aufbau principle, half-filled and completely filled d (or) f orbitals are more stable than partially filled f orbitals.

Hence Eu2+ [Xe] 4f7 5d0 is more stable than Ce2+ [Xe] 4f2 5d0

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Electronic Configuration
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Chapter 4: Transition and Inner Transition Elements - Evaluation [Page 129]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board
Chapter 4 Transition and Inner Transition Elements
Evaluation | Q 20. | Page 129
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