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Why does iodine exhibit a slight metallic character? - Chemistry (Theory)

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Question

Why does iodine exhibit a slight metallic character?

Short Answer
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Solution

  1. Electronegativity decreases down the halogen group; iodine has lower electronegativity than lighter halogens.
  2. Because of this, iodine shows metallic luster unlike other halogens.
  3. Iodine can form positive ions like I+ and I3+ under specific conditions, which is a metallic property.
  4. These factors indicate iodine's tendency towards metallic behaviour, though it is still predominantly non-metallic.

This is due to its lower electronegativity and ability to form positive oxidation states.

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