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Question
Which of the following orders are correct as per the properties mentioned against each?
| (i) | \[\ce{As2O3 < SiO2 < P2O3 < SO2}\] | Acid strength. |
| (ii) | \[\ce{AsH3 < PH3 < NH3}\] | Enthalpy of vapourisation. |
| (iii) | \[\ce{S < O < Cl < F}\] | More negative electron gain enthalpy. |
| (iv) | \[\ce{H2O > H2S > H2Se > H2Te}\] | Thermal stability. |
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Solution
| (i) | \[\ce{As2O3 < SiO2 < P2O3 < SO2}\] | Acid strength. |
| (iv) | \[\ce{H2O > H2S > H2Se > H2Te}\] | Thermal stability. |
Explanation:
Acidic strength of oxides in a group decreases down the group and increases along a period from left to right.
Thermal stability of hydrides of group 16 decreases down the group.
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