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Which from following tests decides the straight chain structure of glucose?

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Question

Which from following tests decides the straight chain structure of glucose?

Options

  • Glucose forms oxime when treated with hydroxylamine.

  • Glucose forms cyanohydrin when treated with HCN.

  • Glucose forms gluconic acid when treated with Br₂ water.

  • Glucose forms n-hexane when prolong heated with HI.

MCQ
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Solution

Glucose forms n-hexane when prolong heated with HI.

Explanation:

The six carbons in glucose molecule form a straight chain was inferred from the following observation:

Glucose gives n-hexane on prolonged heating with HI.

\[CHO(CHOH)_4CH_2OH\longrightarrow CH_3-(CH_2)_4-CH_3\mathrm{n-Hexane}\]

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Theoretical Basis of Organic Reactions
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