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Question
Which from following tests decides the straight chain structure of glucose?
Options
Glucose forms oxime when treated with hydroxylamine.
Glucose forms cyanohydrin when treated with HCN.
Glucose forms gluconic acid when treated with Br₂ water.
Glucose forms n-hexane when prolong heated with HI.
MCQ
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Solution
Glucose forms n-hexane when prolong heated with HI.
Explanation:
The six carbons in glucose molecule form a straight chain was inferred from the following observation:
Glucose gives n-hexane on prolonged heating with HI.
\[CHO(CHOH)_4CH_2OH\longrightarrow CH_3-(CH_2)_4-CH_3\mathrm{n-Hexane}\]
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Theoretical Basis of Organic Reactions
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