Advertisements
Advertisements
Question
What will be the work done on an ideal gas enclosed in a cylinder, when it is compressed by a constant external pressure, pext in a single step as shown in figure. Explain graphically.

Advertisements
Solution
Assumption: Cylinder is filled with one mole gas, and the piston is frictionless. Let the pressure of gas inside be p and the volume of gas be \[\ce{V_{I}}\].
Piston is moved towards the inside to make the external pressure \[\ce{(P_{ext})}\] equal to p. Now, let us assume that this change takes place in a single step, hence, \[\ce{V}\] is the final volume. The work done by the piston is depicted in the graph shown below by shading the area.
PextΔV = AV1 × (V1 – V2)

APPEARS IN
RELATED QUESTIONS
The pressure-volume work for an ideal gas can be calculated by using the expression w = `- int_(v_i)^(v_f) p_(ex) dV`. The work can also be calculated from the pV– plot by using the area under the curve within the specified limits. When an ideal gas is compressed (a) reversibly or (b) irreversibly from volume Vi to Vf. choose the correct option.
A sample of 1.0 mol of a monoatomic ideal gas is taken through a cyclic process of expansion and compression as shown in figure 6.1. What will be the value of ∆H for the cycle as a whole?

How will you calculate work done on an ideal gas in a compression, when change in pressure is carried out in infinite steps?
Represent the potential energy/enthalpy change in the following processes graphically.
(a) Throwing a stone from the ground to roof.
(b) \[\ce{1/2 H2(g) + 1/2 Cl2 (g) ⇌ HCl (g) Δ_rH^Θ = - 92.32 kJ mol^{-1}}\]
In which of the processes potential energy/enthalpy change is contributing factor to the spontaneity?
1.0 mol of a monoatomic ideal gas is expanded from state (1) to state (2) as shown in figure. Calculate the work done for the expansion of gas from state (1) to state (2) at 298 K.
An ideal gas is allowed to expand against a constant pressure of 2 bar from 10 L to 50 L in one step. Calculate the amount of work done by the gas. If the same expansion were carried out reversibly, will the work done be higher or lower than the earlier case? (Given that 1 L bar = 100 J)
Match the following :
| A | B |
| (i) Adiabatic process | (a) Heat |
| (ii) Isolated system | (b) At constant volume |
| (iii) Isothermal change | (c) First law of thermodynamics |
| (iv) Path function | (d) No exchange of energy and matter |
| (v) State function | (e) No transfer of heat |
| (vi) ΔU = q | (f) Constant temperature |
| (vii) Law of conservation of energy | (g) Internal energy |
| (viii) Reversible process | (h) Pext = o |
| (ix) Free expansion | (i) At constant pressure |
| (x) ΔH = q | (j) Infinitely slow process which proceeds through a series of equilibrium states. |
| (xi) Intensive property | (k) Entropy |
| (xii) Extensive property | (l) Pressure |
| (m) Specific heat |
Graphically show the total work done in an expansion when the state of an ideal gas is changed reversibly and isothermally from \[\ce{(p_i, V_i)}\] to \[\ce{(p_f , V_f )}\]. With the help of a pV plot compare the work done in the above case with that carried out against a constant external pressure \[\ce{p_f}\].
For silver Cp (J K-1 mol-1) = 23 + 0.01 T. If the temperature (T) of 3 moles of silver is raised from 300 K to 1000 K at 1 atom pressure, the value of ΔH will be close to ______.
Calculate the work involved when 1 mol of an ideal gas is compressed reversibly from 1.00 bar to 5.00 bar at a constant temperature of 300 K ______.
The net work done in the following cycle for one mol of an ideal gas will be ______ (in calorie), where in process BC, PT = constant. (R = 2 cal/mol-K).

1 mole of an ideal monoatomic gas initially at 1 atm and 300 K experiences a process by which pressure is doubled. The nature of the process is unspecified but 6. ΔU = 900 cal. The final volume will be ______ l.
[Given : R = 0.08 atm lit. I mol/K = 2 Cal/K/mol J]
Find the work done when 2 moles of hydrogen expand isothermally from 15 to 50 litres against a constant pressure of 1 atm at 25°C.
Five moles of an ideal gas at 1 bar and 298 K is expanded into the vacuum to double the volume. The work done is ______.
