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What happens when ethanol is treated with phosphorus tribromide?

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Question

What happens when ethanol is treated with phosphorus tribromide?

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Solution

When ethanol (CH3CH2OH) is treated with phosphorus tribromide (PBr3), it undergoes a substitution reaction, resulting in the conversion of the hydroxyl group (–OH) into a bromine atom (Br). This produces ethyl bromide (C2H5Br).

\[\ce{\underset{ethanol}{CH3CH2OH} + \underset{tribromide}{\underset{phosphorus}{PBr3}} -> \underset{ethyl bromide}{CH3CH2Br} + \underset{phosphorous acid}{H3PO3}}\]

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Chapter 6: Haloalkanes and Haloarenes - REVIEW EXERCISES [Page 585]

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Nootan Chemistry [English] Class 12 ISC
Chapter 6 Haloalkanes and Haloarenes
REVIEW EXERCISES | Q 10.23 (iii) | Page 585
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