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Question
Two liquids A and B can form an ideal solution only when the A-B molecular interaction forces are ______ to the A-A or B-B interaction forces.
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Solution
Two liquids A and B can form an ideal solution only when the A-B molecular interaction forces are similar to the A-A or B-B interaction forces.
Explanation:
Ideal solutions follow Raoult’s Law perfectly. This happens when no heat is absorbed or evolved and no volume change occurs upon mixing, i.e., ΔHmix = 0, ΔVmix = 0.
This condition is satisfied only when the intermolecular interactions between A and B molecules are the same as the interactions between A and A molecules and also the same as the interactions between B and B molecules.
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