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Question
The formation of complex compounds, finds application in the extraction of some metals. Furnish one example to support the above statement.
Long Answer
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Solution
- The formation of complex compounds plays an important role in the extraction of certain metals by increasing their solubility or selectivity during the process.
- A classic example is the extraction of gold (Au) using cyanide ions (CN−). In this method, gold is treated with an aqueous solution of sodium cyanide (NaCN) in the presence of oxygen.
- Gold forms a soluble complex, [Au(CN)2]−, which can then be separated from the ore:
\[\ce{4Au + 8CN^- + O2 + H2O → 4[Au(CN)2]^- + 4OH^-}\] - This process is known as cyanidation.
- Cyanidation allows for the efficient extraction of gold from low-grade ores.
- This example demonstrates the practical importance of complex formation in metallurgy.
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Chapter 9: Coordination Compounds - Review Exercises [Page 541]
