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Question
The following reaction is feasible or not feasible and why?
\[\ce{Br2 + 2NaI -> 2NaBr + I2}\]
Long Answer
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Solution
- This is a halogen displacement reaction where bromine (Br2) reacts with sodium iodide (NaI).
- Bromine is more reactive than iodine, so it can displace iodine from sodium iodide.
- The reaction forms sodium bromide (NaBr) and iodine (I2).
- To check feasibility, EMF values of half reactions (Br2/Br−) and (I2/I−) are compared.
- Bromine has a higher standard electrode potential (+1.09 V) than iodine (+0.54 V).
- The EMF of the cell is positive, implying the reaction is spontaneous and feasible.
Therefore, the reaction proceeds as bromine displaces iodine from sodium iodide.
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Chapter 7: p-Block Elements - SHORT ANSWER TYPE QUESTIONS [Page 448]
