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Tamil Nadu Board of Secondary EducationHSC Science Class 11

State the third law of thermodynamics. - Chemistry

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Question

State the third law of thermodynamics.

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Solution

The third law of thermodynamics states that the entropy of a pure crystalline substance at absolute zero is zero. Otherwise, it can be stated that it is impossible to lower the temperature of an object to absolute zero in a finite number of steps. Mathematically,

`lim_(T->0)` S = 0 for a perfectly ordered crystalline state.

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Spontaneity - Absolute Entropy and Third Law of Thermodynamics
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Chapter 7: Thermodynamics - Evaluation [Page 225]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 11 TN Board
Chapter 7 Thermodynamics
Evaluation | Q II. 17. | Page 225
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