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Show that the heat absorbed at constant pressure is equal to the change in enthalpy of the system.

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Question

Show that the heat absorbed at constant pressure is equal to the change in enthalpy of the system.

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Solution

Heat absorbed at constant pressure, QP = Δ U + Pext Δ V

Enthalpy, H = U + PV. Change in enthalpy at constant pressure is given by Δ H = Δ U + P Δ V

If inside pressure (P) and outside pressure Pext are the same, QP = Δ U + P Δ V = Δ H.

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