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Out of physisorption and chemisorption, which decreases with an increase in temperature?

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Question

Out of physisorption and chemisorption, which decreases with an increase in temperature?

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Solution

Physisorption decreases with an increase in temperature due to weakening van der Waals forces. Chemisorption, however, first increases and then decreases with temperature rise because it involves activation energy and chemical bond formation. Thus, physisorption decreases with temperature increase.

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