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Question
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH2C(CH3)2CH2I
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Solution
\[\begin{array}{cc}
\phantom{.......}\ce{CH3}\\
\phantom{....}|\\
\ce{\overset{4}{C}H3 - \overset{3}{C}H2 - \overset{2}{C} - \overset{1}{C}H2 - I}\\
\phantom{....}|\\
\phantom{.......}\ce{CH3}
\end{array}\]
IUPAC Name: 1-iodo-2,2-dimethylbutane
Classify: 1° alkyl halide
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(a) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
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\end{array}\]
(b) \[\begin{array}{cc}
\ce{D}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
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\end{array}\]
(c) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
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\end{array}\]
(d) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{H}\phantom{...}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
Which is the correct IUPAC name for \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - Br}\\
\phantom{}|\phantom{.......}\\
\phantom{}\ce{C2H5}\phantom{....}
\end{array}\]?
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