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Question
How would you account for the following?
All scandium salts are white.
Short Answer
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Solution
- Scandium salts are white because scandium forms Sc3+ ions with an empty d-orbital (electronic configuration 3d0).
- The absence of d-d electronic transitions means no colors are produced in their compounds.
- Additionally, the salts are ionic and lack any charge transfer bands that could cause coloration.
Therefore, all scandium salts appear white due to these electronic and structural features.
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Chapter 8: d-and ƒ-Block Elements - REVIEW EXERCISES [Page 492]
