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Question
How many coulombs of electricity are required for reduction of 1 mole of \[\ce{Cr2O^{2-}_{ 7}}\] to Cr3+?
Numerical
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Solution
To calculate the coulombs of electricity required for the reduction of 1 mole of \[\ce{Cr2O^{2-}_{ 7}}\] to Cr3+, follow these steps:
\[\ce{Cr2O^{2-}_{ 7} + 14H+ + 6e− -> 2Cr^{3+} + 7H2O}\]
1 mole of \[\ce{Cr2O^{2-}_{ 7}}\] requires 6 moles of electrons.
By using Faraday’s law
Charge (Q) = n × F ...(i)
Where:
n = 6 mol e− (from above)
F = 96500 C/mol e−
Putting these values in equation (i), we get
Q = 6 × 96500
Q = 579000 C
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Chapter 3: Electrochemistry - REVIEW EXERCISES [Page 179]
