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Question
How can you prepare Cl2 from HCl ? Write reaction only.
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Solution
\[\ce{MnO2_{(s)} + 4HCl_{(aq)} -> MnCl2_{(aq)} + 2H2O_{(l)} + Cl2_{(g)}}\]
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Assertion: \[\ce{NaCl}\] reacts with concentrated \[\ce{H2SO4}\] to give colourless fumes with pungent smell. But on adding \[\ce{MnO2}\] the fumes become greenish yellow.
Reason: \[\ce{MnO2}\] oxidises \[\ce{HCl}\] to chlorine gas which is greenish yellow.
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