Advertisements
Advertisements
Question
Give one test to differentiate \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]Cl}\].
Advertisements
Solution
\[\ce{[Co(NH3)5Cl]SO4 -> [Co(NH3)5Cl]^{+2} + SO^2-_4}\]
\[\ce{[Co(NH3)5SO4]Cl -> [Co(NH3)5Cl]SO4}\]
1. Aqueous solution of (a) gives sulphate ion. When the addition of BaCl, solution (a) gives a white precipitate of BaSO4. But (b) does not give any precipitate.
2. Aqueous solution of (b) gives chloride ion. When the addition of AgNO3 solution (b) gives curdy white precipitate of AgCl. But (a) does not give any precipitate.
APPEARS IN
RELATED QUESTIONS
The sum of primary valence and secondary valence of the metal M in the complex [M(en)2(Ox)]Cl is ____________.
As per IUPAC guidelines, the name of the complex [Co(en)2(ONO)Cl]Cl is
Crystal field stabilization energy for high spin d5 octahedral complex is ____________.
Choose the correct statement.
Arrange the following in order of increasing molar conductivity.
i) \[\ce{Mg[Cr(NH3) (Cl)5]}\]
ii) \[\ce{[Cr(NH3)5 Cl]3 [CoF6]2}\]
iii) \[\ce{[Cr(NH3)3 Cl3]}\]
In an octahedral crystal field, draw the figure to show the splitting of d orbitals.
Why tetrahedral complexes do not exhibit geometrical isomerism.
What is crystal field stabilization energy (CFSE)?
Discuss briefly the nature of bonding in metal carbonyls.
Write the oxidation state, coordination number, nature of ligand, magnetic property and electronic configuration in octahedral crystal field for the complex \[\ce{K4[Mn(CN)6]}\].
