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Question
For the reaction \[\ce{2A + B + C -> A2B + C}\], rate law has been determined to be, Rate = k [A] [B]2. If the rate constant k = 2.0 × 10−6 mol−2Ls−1, what will be the initial rate of the reaction with [A] = 0.1 mol L−1, [B] = 0.2 mol L−1 and [C = 0.8 mol L−1?
Numerical
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Solution
Given:
k = 2.0 × 10−6 mol−2Ls−1
[A] = 0.1 mol L−1
[B] = 0.2 mol L−1
[C] = 0.8 mol L−1 (but not in the rate law, so it's irrelevant here)
Rate = k [A] [B]2
= 2.0 × 10−6 × (0.1) × (0.2)2
= 2.0 × 10−6 × 0.1 × 0.04
= 2.0 × 10−6 × 0.004
= 8.0 × 10−9 mol L−1 s−1
∴ The initial rate of the reaction is 8.0 × 10−9 mol L−1 s−1
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