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Question
Discuss the occurrence of the inner transition elements in nature.
Very Long Answer
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Solution
- Inner transition elements consist of lanthanoids and actinoids, and belong to the f-block of the periodic table.
- They are called inner transition elements because their differentiating electrons enter the (n − 2) f-subshell.
- Lanthanoids range from atomic number 58 (Cerium) to 71 (Lutetium), while actinoids range from 90 (Thorium) to 103 (Lawrencium).
- These elements are rare in nature and are often referred to as rare earth elements due to their scarcity in Earth’s crust.
- Lanthanoids occur naturally mostly in minerals such as monazite and bastnäsite.
- Actinoids, especially uranium and thorium, are found in nature, but many actinoids are synthetic and not naturally abundant.
- Lanthanoids and actinoids have similar properties due to the filling of 4f and 5f orbitals, respectively.
- Because of their rarity and similar chemical properties, they are difficult to separate from each other in nature.
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Chapter 8: d-and ƒ-Block Elements - LONG ANSWER TYPE QUESTIONS [Page 498]
