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Question
Derive an expression for refraction at a single (convex) spherical surface, i.e., a relation between u, v, R, n1 (rarer medium) and n2 (denser medium), where the terms have their usual meaning.
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Solution
In the figure, XPY is a spherical surface with centre C and radius R, O is the object, and I is the image,

OA and AI are incident and refracted rays; i and r are angles of incidence and refraction.
From the figure,
i = α + γ and r = γ − β
Now, tan α = `(MA)/(MO)` or α = `(MA)/(MO)` ...(When A is very near to P)
Similarly, β = `(MA)/(MI)` and
γ = `(MA)/(MC)`
From snells law:
`(sin i)/(sin r) = n_2/n_1`
If i and r are small,
`i/r = n_2/n_1`
Also, MO ∼ PO, MC ∼ PC, MI ∼ PI,
PO = −u, PI = v and PC = R,
∴ α = `(PA)/(PO) = (PA)/-u`
β = `(PA)/(PI)`
γ = `(PA)/(PC) = (PA)/R`
i = α + γ
= `PA (-1/u + 1/R)` and
r = γ − β
= `PA (1/R - 1/v)`
Now, `i/r = n_2/n_1`
⇒ n1i = n2r
⇒ `PA (-1/u + 1/R)n_1 = PA (1/R - 1/v)n_2`
⇒ `-n_1/u + n_1/R = n_2/R - n_2/v`
⇒ `n_2/v - n_1/u = (n_2 - n_1)/R`
