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Question
Decide giving reason which one of the following pairs has the property indicated:
Fe or Cu has higher melting point.
Give Reasons
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Solution
- Iron (Fe) has a higher melting point than Copper (Cu).
- Fe has more unpaired electrons in its 3d orbitals compared to Cu, leading to stronger metallic bonding.
- Stronger metallic bonds mean more energy is needed to break them, resulting in a higher melting point for Fe.
- Cu has a nearly filled d-subshell (3d10), with fewer unpaired electrons, so metallic bonding is weaker.
Therefore, the stronger bonding of Fe gives it a higher melting point than Cu.
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