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Question
Decide giving reason which one of the following pairs has the property indicated:
Co2+ or Ni2+ has lower magnetic moment.
Give Reasons
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Solution
- The magnetic moment depends on the number of unpaired electrons in the ion.
- Co2+ has 3 unpaired electrons (electronic configuration: [Ar] 3d7), while Ni2+ has two unpaired electrons (configuration: [Ar] 3d8).
- More unpaired electrons mean a higher magnetic moment; hence, Co2+ has a higher magnetic moment than Ni2+.
- Therefore, Ni2+ has a lower magnetic moment than Co2+ because it has fewer unpaired electrons in its d-orbitals.
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Chapter 8: d-and ƒ-Block Elements - REVIEW EXERCISES [Page 477]
