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Question
Calculate the oxidation number of Ag in K[Ag(CN)2].
Numerical
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Solution
K+ → charge = +1
Complex ion: [Ag(CN)2]– → overall charge = –1
Let oxidation number of Ag = x
Each CN = –1
Total from 2 CN = –2
Putting the value in formula,
∴ x + (–2) = –1
x – 2 = –1
x = –1 + 2
x = +1
∴ The oxidation number of Ag in K[Ag(CN)2] is +1.
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