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Question
Calculate the osmotic pressure of solution containing 0.822 gm of sucrose in 300 mL of water at 298 K.
[Given: Molar mass of sucrose 342 g/mol, R = 0.08205 dm3. atm. K−1. mol−1]
Numerical
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Solution
Given: Mass of sucrose (w) = 0.822 g
Molar mass of sucrose (M) = 342 g/mol
Volume of solution (V) = 300 mL = 0.300 L
Temperature (T) = 298 K
R = 0.08205 dm3. atm. K−1. mol−1
Number of moles of sucrose (n) = `w/M`
= `0.822/342`
= 0.0024 mol
Osmotic pressure (π) = `n/V RT`
= `0.0024/0.300 xx 0.08205 xx 298`
= 0.008 × 0.08205 × 298
= 0.1956 atm
∴ The osmotic pressure of the solution is 0.1956 atm.
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